INFLUENCE OF CARBONATE TYPE ON TRANSPORT CHARACTERISTICS OF SiC-BASED CERAMIC MEMBRANES

Authors

DOI:

https://doi.org/10.20535/kpisn.2023.1-4.291501

Abstract

Background. Ceramic membranes have recently attracted particular attention due to their thermal and chemical resistance, ability to be used in aggressive environments, and long service life. Among ceramic membranes, silicon carbide membranes deserve special attention due to their high strength. However, the high cost of such membranes and the controllability of porous characteristics, which significantly affect the transportation characteristics, remain an unresolved problem. Therefore, it is extremely important to investigate ways to reduce the annealing temperature of SiC membranes and control their porosity.

Objective. The aim of this work is to determine the effect of the type of carbonate on the physicochemical properties and transport characteristics of ceramic membranes based on silicon carbide. The ceramic membranes were obtained by pressing, to which borax (to reduce the annealing temperature) and carbonates (as a pore forming agent) were added.

Methods. Method of pressing and sintering with different composition of carbonates. Analysis of the obtained ceramic membranes by the diffraction method and scanning electron microscopy.

Results. It has been shown that the addition of sodium carbonate results in the formation of a new phase, sodium aluminosilicate, while no new phases were detected when ammonium bicarbonate was used. The morphology of the synthesized ceramic membranes has a granular structure characterized by pores ranging in size from 13 to 21 μm and a specific surface area of 1.5–1.9 m3/g. The investigated transport characteristics of ceramic membranes indicate that the use of ammonium bicarbonate allows to obtain a ceramic membrane with a sufficiently high throughput, which can be recommended for use in the field of microfiltration.

Conclusions. Ammonium bicarbonate is a more promising pore-forming additive for ceramic membranes based on silicon carbide. Further research will focus on studying the effect of the defoamer content on the transport and mechanical properties of ceramic membranes.

Author Biography

Tetiana Dontsova

National Technical University of Ukraine

“Igor Sikorsky Kyiv Polytechnic Institute”, Faculty of Chemical Technology, Department of Inorganic Substances, Water Treatment and General Chemical Technology

References

C. Li et al., “Ceramic nanocomposite membranes and membrane fouling: A review”, Water Research, vol. 175, p. 115674, 2020. doi: 10.1016/j.watres.2020.115674

R.B. Merlet et al., “Hybrid ceramic membranes for organic solvent nanofiltration: State-of-the-art and challenges”, Journal of Membrane Science, vol. 599, p. 117839, 2020. doi: 10.1016/j.memsci.2020.117839

M.B. Asif et al., “Ceramic membrane technology for water and wastewater treatment: A critical review of performance, full-scale applications, membrane fouling and prospects”, Chemical Engineering Journal, vol. 418, p. 129481, 2021. doi: 10.1016/j.cej.2021.129481

J. Liu et al., “Coupling ferrate pretreatment and in-situ ozonation/ceramic membrane filtration for wastewater reclamation: Water quality and membrane fouling”, Journal of Membrane Science, vol. 590, p. 117310, 2019. doi: 10.1016/j.memsci.2019.117310

S.M. Samaei et al., “The application of pressure-driven ceramic membrane technology for the treatment of industrial wastewaters – A review”, Separation and Purification Technology, vol. 200, pp. 198–220, 2018. doi: 10.1016/j.seppur.2018.02.041

G. Zhang et al., (2023), “Asymmetric alumina-based ultrathin composite ceramic membranes with interfacial modification of black talc nanosheets”, Ceramics International, no. 49(15), pp. 25371–25380, 2023. doi: 10.1016/j.ceramint.2023.05.073

E. Eray et al., “A roadmap for the development and applications of silicon carbide membranes for liquid filtration: Recent advancements, challenges, and perspectives”, Chemical Engineering Journal, vol. 414, p. 128826, 2021. doi: 10.1016/j.cej.2021.128826

M. Chen et al., “Highly permeable silicon carbide-alumina ultrafiltration membranes for oil-in-water filtration produced with low-pressure chemical vapor deposition”, Separation and Purification Technology, vol. 253, p. 117496, 2020. doi: 10.1016/j.seppur.2020.117496

M. Qiu et al., “1.11 Ceramic Membranes”, In Elsevier eBooks, pp. 270–297, 2017. doi: 10.1016/b978-0-12-409547-2.12243-7

H. Kaur et al., “Effect of carbonates composition on the permeation characteristics of low-cost ceramic membrane supports”, Journal of Industrial and Engineering Chemistry, vol. 44, pp. 185–194, 2016. doi: 10.1016/j.jiec.2016.08.026

H. Aripin et al., “Characterization of Ceramic Membrane based on Calcium Carbonate from Onyx Stone and Its Application for Coconut Sap Treatment”, International Journal of Engineering, no. 35(2), pp. 300–306, 2022. doi: 10.5829/ije.2022.35.02b.05

J. Locs et al., “Ammonium hydrogen carbonate provided viscous slurry foaming—A novel technology for the preparation of porous ceramics”, Journal of the European Ceramic Society, no. 33(15-16), pp. 3437–3443, 2013. doi: 10.1016/j.jeurceramsoc.2013.06.010

Published

2024-04-22